The thermodynamic cost of driving quantum systems by their boundaries
نویسنده
چکیده
The laws of thermodynamics put limits to the efficiencies of thermal machines. Analogues of these laws are now established for quantum engines weakly and passively coupled to the environment providing a framework to find improvements to their performance. Systems whose interaction with the environment is actively controlled do not fall in that framework. Here we consider systems actively and locally coupled to the environment, evolving with a so-called boundary-driven Lindblad equation. Starting from a unitary description of the system plus the environment we simultaneously obtain the Lindblad equation and the appropriate expressions for heat, work and entropy-production of the system extending the framework for the analysis of new, and some already proposed, quantum heat engines. We illustrate our findings in spin 1/2 chains and explain why an XX chain coupled in this way to a single heat bath relaxes to thermodynamic-equilibrium while and XY chain does not. Additionally, we show that an XX chain coupled to a left and a right heat baths behaves as a quantum engine, a heater or refrigerator depending on the parameters, with efficiencies bounded by Carnot efficiencies.
منابع مشابه
Optimizing Teleportation Cost in Multi-Partition Distributed Quantum Circuits
There are many obstacles in quantum circuits implementation with large scales, so distributed quantum systems are appropriate solution for these quantum circuits. Therefore, reducing the number of quantum teleportation leads to improve the cost of implementing a quantum circuit. The minimum number of teleportations can be considered as a measure of the efficiency of distributed quantum systems....
متن کاملکالری و آب در طراحی دارو
Elucidation of how the thermodynamic parameters are determined by the molecular structures in a bimolecular interactions is becoming a fundamental driving force in the rational design of drugs. If we can determine the structure of the target and the potential drug we should be able to predict the equilibrium constant for their interaction based on simple relationships. With this information the...
متن کاملThermodynamic analysis of nanocrystalline solid solution formation in the W-Co-Si ternary system by mechanical alloying
Co3W2Si intermetallic compound was synthesized by mechanical alloying (MA) of W, Co and Si elemental powder mixtures. The phase composition of the milled products was evaluated by X-ray diffraction (XRD) analysis. Morphological evolutions were characterized by transmission electron microscopy (TEM). The results showed that high energy ball milling performed in the present work led to the format...
متن کاملQuantum Mechanical Approach for the Catalytic Mechanism of Dinuclear Zinc Metallo-β-lactamase by Penicillin and Cephalexin: Kinetic and Thermodynamic Points of View
Metallo-β-lactamases (MβL) catalyzing the hydrolytic cleavage of the four-membered β-lactam ring in broad spectrum of antibiotics and therefore inactivating the drug; However, the mechanism of these enzymes is still not well understood. Electronic structure and electronic energy of metallo-β-lactamase active center, two inhibitors of this enzyme including penicillin and cephalexin, and differen...
متن کاملQuantum mechanical investigation of 4-hydroxy phenyl azobenzene adsorption on the boron nitride nanotubes
In this study, the adsorption of 4-hydroxy phenyl-azobenzene on the surface of (4, 0) zigzag open-end boron nitride nanotube (BNNT) has been investigated by quantum calculations. In order to find the preferred adsorption site, different positions and orientations were considered. The impacts of donor-acceptor electron delocalization on the structural and electronic properties and reactivity of ...
متن کامل